 |
Home ©NIST, 2023 Accessibility information |
Contact Us to Submit an Article
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
Title: Mechanism of the pyrolysis of C2HCl5, molecular and radical steps
Journal: Int. J. Chem. Kinet.
Volume: 14
Page(s): 1287 - 1304
Year: 1982
Reference type: Journal article
Squib: 1982BEN/WEI1287-1304
Reaction:
CHCl2C(·)Cl2 → C2HCl3 + ·Cl
Reaction order:
1
Temperature:
300 - 700
K
Rate expression:
2.51x1013 [s-1] e-69842 [±16047 J/mole]/RT
Category: Theory
Data type:
Estimated: thermochemical, kinetic, or other
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 300 | 1.74E1 |
| 325 | 1.50E2 |
| 350 | 9.48E2 |
| 375 | 4.69E3 |
| 400 | 1.90E4 |
| 425 | 6.55E4 |
| 450 | 1.96E5 |
| 475 | 5.24E5 |
| 500 | 1.27E6 |
| 525 | 2.82E6 |
| 550 | 5.85E6 |
| 575 | 1.14E7 |
| 600 | 2.09E7 |
| 625 | 3.65E7 |
| 650 | 6.13E7 |
| 675 | 9.89E7 |
| 700 | 1.54E8 |