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Accessibility information
Author(s):   King, K.D.; Goddard, R.D.
Title:   Very Low-Pressure Pyrolysis (VLPP) of Alkyl Cyanides. II. n-Propyl Cyanide and Isobutyl Cyanide. The Heat of Formation and Stabilization Energy of the Cyanomethyl Radical
Journal:   Int. J. Chem. Kinet.
Volume:   7
Year:   1975
Reference type:   Journal article
Squib:   1975KIN/GOD837

Reaction:   iso-C4H9CNiso-C3H7 + CH2CN
Reaction order:   1
Temperature:   1010 - 1120 K
Rate expression:   2.51x1015 [s-1] e-305973 [±6119 J/mole]/RT
Uncertainty:   2.0
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1010 3.77E-1
1025 6.42E-1
1050 1.51E0
1075 3.41E0
1100 7.42E0
1120 1.35E1