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Author(s):   Loison, J.C.; Daranlot, J.; Bergeat, A.; Caralp, F.; Mereau, R.; Hickson, K.M.
Title:   Gas-Phase Kinetics of Hydroxyl Radical Reactions with C3H6 and C4H8: Product Branching Ratios and OH Addition Site-Specificity
Journal:   J. Phys. Chem. A
Volume:   114
Page(s):   13326 - 13336
Year:   2010
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2010LOI/DAR13326-13336

Reaction:   (E)-2-C4H8 + ·OHH2O + (E)-CH3CH=CHCH2
Reaction order:   2
Reference reaction:   1-C4H8 + ·OH → Products
Reference reaction order:   2
Temperature:   300 K
Pressure:  1.07E-3 - 4.00E-3 bar
Rate expression:   3.0x10-2±1.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   The errors bars represent 95% confidence intervals and include estimated uncertainties in photoionization cross sections.

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