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Title: Gas phase rate coefficients and activation energies for the reaction of butanal and 2-methyl-propane with nitrate radicals
Journal: Int. J. Chem. Kinet.
Volume: 32
Page(s): 294 - 303
Year: 2000
Reference type: Journal article
Squib: 2000ULL/LAN294-303
Reaction:
CH3CH2CH2CHO + NO3 → Products
Reaction order:
2
Temperature:
263 - 364
K
Pressure: 1.02 bar
Rate expression:
1.2x10-12 [cm3/molecule s] e-12131 [±2237 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Experimental procedure:
Flow tube - Data taken vs distance
Excitation technique:
Discharge
Time resolution:
In real time
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 263 | 4.68E-15 |
| 275 | 5.96E-15 |
| 300 | 9.27E-15 |
| 325 | 1.35E-14 |
| 350 | 1.86E-14 |
| 364 | 2.18E-14 |