Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Cabanas, B.; Martin, P.; Salgado, S.; Ballesteros, B.; Martinez, E.
Title:   An Experimental Study on the Temperature Dependence for the Gas-Phase Reactions of NO3 Radical with a Series of Aliphatic Aldehydes
Journal:   J. Atmos. Chem.
Volume:   40
Page(s):   23 - 39
Year:   2001
Reference type:   Journal article
Squib:   2001CAB/MAR23-39

Reaction:   CH3CH2CH2CHO + NO3 → Products
Reaction order:   2
Temperature:   298 - 433 K
Pressure:  1.47E-3 bar
Rate expression:   7.6x10-11 [±9.8x10-11 cm3/molecule s] e-20500 [±4200 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Electron beam
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Nitrate radical generated by F + HNO3 = HF + NO3

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 1.94E-14
300 2.05E-14
325 3.86E-14
350 6.63E-14
375 1.06E-13
400 1.60E-13
425 2.30E-13
433 2.56E-13