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Author(s):   Bedjanian, Y.; Poulet, G.; Le Bras, G.
Title:   Low-Pressure Study of the Reactions of Br Atoms with Alkenes. 3. Reactions with 2-Methyl-2-Butene, 2,3-Dimethyl-2-Butene, and 1-Hexene
Journal:   J. Phys. Chem. A
Volume:   104
Page(s):   577 - 583
Year:   2000
Reference type:   Journal article
Squib:   2000BED/POU577-583

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2000BED/POU577-583   (CH3)2C=CHCH3 + Br· → Adduct  233 - 298   5.20E-16       -1.59E04      2
  2000BED/POU577-583   (CH3)2C=C(CH3)2 + Br· → Adduct  233 - 298   8.40E-16       -1.62E04      2
  2000BED/POU577-583   (CH3)2C=CHCH3 + Br· → Products + HBr  233 - 320   2.10E-11       5446   2.33E-12  2
  2000BED/POU577-583   (CH3)2C=C(CH3)2 + Br· → Products + HBr  233 - 320   2.40E-11       624   1.87E-11  2
  2000BED/POU577-583   1-C6H12 + Br· → Products + HBr  233 - 320   3.25E-12       3534   7.81E-13  2

Search returned 5 records.