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Author(s):   Forst, W.; Caralp, F.
Title:   Microcanonical variational theory of radical recombination by inversion of interpolated partition function. Part 2 - CX3 + O2 (X = H, F, Cl)
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   87
Page(s):   2307 - 2315
Year:   1991
Reference type:   Journal article
Squib:   1991FOR/CAR2307-2315

Reaction:   ·CCl2F + O2 → CCl2FO2
Reaction order:   3
Temperature:   233 - 373 K
Rate expression:   6.15x10-30 [cm6/molecule2 s] (T/298 K)-5.61
Bath gas:   N2
Category:  Experiment
Data type:   RRK(M) extrapolation

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
233 2.45E-29
250 1.65E-29
275 9.65E-30
300 5.92E-30
325 3.78E-30
350 2.49E-30
373 1.75E-30