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Title: Microcanonical variational theory of radical recombination by inversion of interpolated partition function. Part 2 - CX3 + O2 (X = H, F, Cl)
Journal: J. Chem. Soc. Faraday Trans.
Volume: 87
Page(s): 2307 - 2315
Year: 1991
Reference type: Journal article
Squib: 1991FOR/CAR2307-2315
Reaction:
·CF3 + O2 → CF3O2
Reaction order:
2
Temperature:
233 - 373
K
Rate expression:
6.34x10-12 [cm3/molecule s] (T/298 K)-0.27
Bath gas:
N2
Category: Experiment
Data type:
RRK(M) extrapolation
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 233 | 6.78E-12 |
| 250 | 6.65E-12 |
| 275 | 6.48E-12 |
| 300 | 6.33E-12 |
| 325 | 6.20E-12 |
| 350 | 6.07E-12 |
| 373 | 5.97E-12 |