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Title: Mechanisms of thermolytic fragmentation of allyl ethers. I.
Journal: J. Am. Chem. Soc.
Volume: 96
Page(s):
Year: 1973
Reference type: Journal article
Squib: 1973KWA/SAR5234
Reaction:
(CH3)3COCH2CH=CH2 → Acetone + 1-C4H8
Reaction order:
1
Temperature:
792 - 850
K
Pressure: 1.01 bar
Rate expression:
3.39x1013 [s-1] e-228648 [±4573 J/mole]/RT
Uncertainty:
2.1400001
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 792 | 2.82E-2 |
| 800 | 3.99E-2 |
| 825 | 1.13E-1 |
| 850 | 3.02E-1 |