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Author(s):   Blake, P.G.; Shraydeh, B.F.
Title:   The thermal decomposition of fluorinated esters. II. The effect of γ-substitution
Journal:   Int. J. Chem. Kinet.
Volume:   14
Year:   1982
Reference type:   Journal article
Squib:   1982BLA/SHR291

Reaction:   n-C3F7COOC2H5C2H4 + Heptafluoro-1-butanoic acid
Reaction order:   1
Temperature:   626 - 686 K
Pressure:  1.33E-2 - 8.00E-2 bar
Rate expression:   1.95x1012 [s-1] e-183750 [±8314472 J/mole]/RT
Uncertainty:   1.35000002
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
626 9.08E-4
650 3.34E-3
675 1.18E-2
686 1.99E-2