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Title: The thermal decomposition of fluorinated esters. II. The effect of γ-substitution
Journal: Int. J. Chem. Kinet.
Volume: 14
Page(s):
Year: 1982
Reference type: Journal article
Squib: 1982BLA/SHR291
Reaction:
n-C3F7COOC2H5 → C2H4 + Heptafluoro-1-butanoic acid
Reaction order:
1
Temperature:
626 - 686
K
Pressure: 1.33E-2 - 8.00E-2 bar
Rate expression:
1.95x1012 [s-1] e-183750 [±8314472 J/mole]/RT
Uncertainty:
1.35000002
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 626 | 9.08E-4 |
| 650 | 3.34E-3 |
| 675 | 1.18E-2 |
| 686 | 1.99E-2 |