Kinetics Database Logo     Home
©NIST, 2022
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article

Citation

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Bejan, I.; Schurmann, A.; Barnes, I.; Benter, T.
Title:   Kinetics of the gas-phase reactions of OH radicals with a series of trimethylphenols
Journal:   Int. J. Chem. Kinet.
Volume:   44
Page(s):   117 - 124
Year:   2012
Reference type:   Journal article
Squib:   2012BEJ/SCH117-124

Reaction:   Phenol, 2,3,6-trimethyl- + ·OH → Products
Reaction order:   2
Reference reaction:   1,3-Butadiene + ·OH → Products
Temperature:   298 K
Pressure:  1.33E-3 bar
Rate expression:   1.36x10-10 [±2.7x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   The quoted error includes the 2σ statistical error obtained from the linear regression analysys plus a 20% contribution to cover possible errors in the recommended value of the rate coefficient for reference compound with OH, and also the errors arising from the IR spectral subtraction procedure.

View full bibliographic record.