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Title: Rate coefficients for cycloalkyl plus O reactions and product branching in the decomposition of chemically activated cycloalkoxy radicals: an experimental and theoretical study
Journal: Phys. Chem. Chem. Phys.
Volume: 12
Page(s): 8954 - 8968
Year: 2010
Reference type: Journal article
Squib: 2010HOY/MAA8954-8968
Reaction:
Cyclooctyl radical + O· → CH2=CHCH2CH2CHO + 1-C3H7
Reaction order:
2
Reference reaction:
Cyclooctyl radical + O· → Products
Reference reaction order:
2
Temperature:
298
K
Rate expression:
1.0x10-2
Category: Theory
Data type:
Transition state theory
Pressure dependence:
Rate constant is low pressure limit
Comments:
Reaction potential energy surface was studied using quantum chemistry and product branching was calculated using RRKM.
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