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Author(s):   Brownsword, R.A.; Gatenby, S.D.; Herbert, L.B.; Smith, I.W.M.; Stewart, D.W.A.; Symonds, A.C.
Title:   Kinetics of reactions between neutral free radicals. Rate constants for the reaction of CH radicals with N atoms between 216 and 584 K
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   92
Page(s):   723 - 727
Year:   1996
Reference type:   Journal article
Squib:   1996BRO/GAT723-727

Reaction:   ·CH + N2CHN2
Reaction order:   2
Temperature:   216 - 584 K
Pressure:  1.33E-3 - 8.00E-3 bar
Rate expression:   2.51x10-14 [cm3/molecule s] (T/298 K)-3.40
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
216 7.49E-14
225 6.52E-14
250 4.56E-14
275 3.29E-14
300 2.45E-14
325 1.87E-14
350 1.45E-14
375 1.15E-14
400 9.22E-15
425 7.50E-15
450 6.18E-15
475 5.14E-15
500 4.32E-15
525 3.66E-15
550 3.12E-15
575 2.68E-15
584 2.55E-15