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Accessibility information
Author(s):   Fulle, D.; Hippler, H.
Title:   The high-pressure range of the reaction of CH(2II) with N2
Journal:   J. Chem. Phys.
Volume:   105
Page(s):   5423 - 5430
Year:   1996
Reference type:   Journal article
Squib:   1996FUL/HIP5423-5430

Reaction:   ·CH + N2CHN2
Reaction order:   3
Temperature:   200 - 500 K
Pressure:  1.01 - 152 bar
Rate expression:   1.4x10-31 [±3.03x10-32 cm6/molecule2 s] (T/298 K)(-2.60±0.49)
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
200 3.95E-31
225 2.91E-31
250 2.21E-31
275 1.73E-31
300 1.38E-31
325 1.12E-31
350 9.22E-32
375 7.71E-32
400 6.52E-32
425 5.57E-32
450 4.80E-32
475 4.17E-32
500 3.65E-32