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Author(s):   Le Picard, S.D.; Canosa, A.; Rowe, B.R.; Brownsword, R.A.; Smith, I.WM.
Title:   Determination of the limiting low pressure rate constants of the reactions of CH with N2 and CO: a CRESU measurement at 53 K
Journal:   J. Chem. Soc. Farad. Trans.
Volume:   94
Page(s):   2889 - 2893
Year:   1998
Reference type:   Journal article
Squib:   1998LEP/CAN2889-2893

Reaction:   ·CH + N2CHN2
Reaction order:   3
Temperature:   53.00 - 584 K
Pressure:  4.00E-4 - 6.00E-3 bar
Rate expression:   1.6x10-31 [cm6/molecule2 s] (T/298 K)-2.20
Category:  Experiment
Data type:   Experimental value and limited review
Pressure dependence:   Rate constant is low pressure limit
Experimental procedure:   Laval nozzle
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm6/molecule2 s]
53.00 7.14E-30
100 1.77E-30
150 7.24E-31
200 3.85E-31
250 2.35E-31
300 1.58E-31
350 1.12E-31
400 8.37E-32
450 6.46E-32
500 5.12E-32
550 4.16E-32
584 3.64E-32