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Title: Linear free-energy relationship involving ortho substituents in gas-phase reactions. XVII
Journal: J. Org. Chem.
Volume: 34
Page(s): 2090 - 2095
Year: 1969
Reference type: Journal article
Squib: 1969SMI/LUM2090-2095
Reaction:
Carbonic acid p,α-dimethylbenzyl methyl ester → 4-Methylstyrene + CH3OC(O)OH
Reaction order:
1
Reference reaction:
Carbonic acid methyl α-methylbenzyl ester → Styrene + CH3OC(O)OH
Reference reaction order:
1
Temperature:
619
K
Rate expression:
1.7
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Thermal
Analytical technique:
Pressure measurement
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