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Accessibility information
Author(s):   Campbell, M.L.
Title:   Temperature Dependent Rate Constants for the Reactions of Gas Phase Lanthanides with CO2
Journal:   Phys. Chem. Chem. Phys.
Volume:   1
Page(s):   3731 - 3735
Year:   1999
Reference type:   Journal article
Squib:   1999CAM3731-3735

Reaction:   CO2 + Nd → Products
Reaction order:   2
Temperature:   298 - 623 K
Pressure:  6.67E-3 bar
Rate expression:   3.3x10-10 [±6.0x10-1 cm3/molecule s] e-12000 [±800 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 2.60E-12
300 2.69E-12
325 3.89E-12
350 5.34E-12
375 7.03E-12
400 8.94E-12
425 1.11E-11
450 1.34E-11
475 1.58E-11
500 1.84E-11
525 2.11E-11
550 2.39E-11
575 2.68E-11
600 2.98E-11
623 3.25E-11