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Title: Kinetics and modeling of the thermal reaction of propene at 800 K. Part I. Pure propene
Journal: Int. J. Chem. Kinet.
Volume: 28
Page(s): 829 - 847
Year: 1996
Reference type: Journal article
Squib: 1996BAR/MAR829-847
Reaction:
CH3CH=CH2 + CH3CH=CH2 → Methylcyclopentane
Reaction order:
2
Temperature:
762 - 811
K
Pressure: 4.00E-2 - 0.27 bar
Rate expression:
4.17x10-12 [cm3/molecule s] e-195390 [J/mole]/RT
Bath gas:
CH3CH=CH2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 762 | 1.68E-25 |
| 775 | 2.82E-25 |
| 800 | 7.29E-25 |
| 811 | 1.09E-24 |