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Title: Chlorine abstraction reactions of fluorine. Part 3.-Thermochemical data for chlorofluoroalkanes
Journal: J. Chem. Soc. Faraday Trans. 1
Volume: 68
Page(s):
Year: 1972
Reference type: Journal article
Squib: 1972FOO/TAI1121
Reaction:
CFCl3 + ·F → Products
Reaction order:
2
Reference reaction:
CFCl2CFCl2 + ·F → Products
Reference reaction order:
2
Temperature:
589 - 733
K
Pressure: 1.87E-2 - 7.07E-2 bar
Rate expression:
2.0x10-1 e20786 [±8314472 J/mole]/RT
Uncertainty:
1.3200000524520874
Bath gas:
Ar
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 589 | 1.39E1 |
| 600 | 1.29E1 |
| 625 | 1.09E1 |
| 650 | 9.36E0 |
| 675 | 8.12E0 |
| 700 | 7.11E0 |
| 725 | 6.29E0 |
| 733 | 6.06E0 |