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Author(s):   Foon, R.; Tait, K.B.
Title:   Chlorine abstraction reactions of fluorine. Part 3.-Thermochemical data for chlorofluoroalkanes
Journal:   J. Chem. Soc. Faraday Trans. 1
Volume:   68
Year:   1972
Reference type:   Journal article
Squib:   1972FOO/TAI1121

Reaction:   CF2Cl2 + ·F → Products
Reaction order:   2
Reference reaction:   CF2Cl-CF2Cl + ·F → Products
Reference reaction order:   2
Temperature:   596 - 747 K
Pressure:  1.87E-2 - 7.07E-2 bar
Rate expression:   1.09 e6394 [±8314472 J/mole]/RT
Uncertainty:   1.0800000429153442
Bath gas:   Ar
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
596 3.96E0
600 3.93E0
625 3.73E0
650 3.56E0
675 3.41E0
700 3.27E0
725 3.15E0
747 3.05E0