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Title: Chlorine abstraction reactions of fluorine. Part 3.-Thermochemical data for chlorofluoroalkanes
Journal: J. Chem. Soc. Faraday Trans. 1
Volume: 68
Page(s):
Year: 1972
Reference type: Journal article
Squib: 1972FOO/TAI1121
Reaction:
CF2Cl2 + ·F → ·CClF2 + ClF
Reaction order:
2
Temperature:
664 - 684
K
Pressure: 1.87E-2 - 7.07E-2 bar
Rate expression:
2.62x10-11 [cm3/molecule s] e-69842 [±1397 J/mole]/RT
Uncertainty:
1.5800000429153442
Bath gas:
Ar
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 664 | 8.41E-17 |
| 675 | 1.03E-16 |
| 684 | 1.22E-16 |