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Author(s):   Millward, G.E.; Tschuikow-Roux, E.
Title:   A kinetic analysis of the shock wave decomposition of 1,1,1,2-tetrafluoroethane
Journal:   J. Phys. Chem.
Volume:   76
Page(s):   292 - 298
Year:   1972
Reference type:   Journal article
Squib:   1972MIL/TSC292-298

Reaction:   CF3CH2FC2HF3 + HF
Reaction order:   1
Temperature:   1170 - 1410 K
Pressure:  3.80 - 5.07 bar
Rate expression:   2.63x1013 [s-1] e-295995 [±5920 J/mole]/RT
Uncertainty:   1.909999966621399
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1170 1.61E0
1175 1.83E0
1200 3.43E0
1225 6.29E0
1250 1.13E1
1275 1.97E1
1300 3.36E1
1325 5.64E1
1350 9.28E1
1375 1.50E2
1400 2.38E2
1410 2.85E2