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Title: A kinetic analysis of the shock wave decomposition of 1,1,1,2-tetrafluoroethane
Journal: J. Phys. Chem.
Volume: 76
Page(s): 292 - 298
Year: 1972
Reference type: Journal article
Squib: 1972MIL/TSC292-298
Reaction:
CF3CH2F → C2HF3 + HF
Reaction order:
1
Temperature:
1170 - 1410
K
Pressure: 3.80 - 5.07 bar
Rate expression:
2.63x1013 [s-1] e-295995 [±5920 J/mole]/RT
Uncertainty:
1.909999966621399
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1170 | 1.61E0 |
| 1175 | 1.83E0 |
| 1200 | 3.43E0 |
| 1225 | 6.29E0 |
| 1250 | 1.13E1 |
| 1275 | 1.97E1 |
| 1300 | 3.36E1 |
| 1325 | 5.64E1 |
| 1350 | 9.28E1 |
| 1375 | 1.50E2 |
| 1400 | 2.38E2 |
| 1410 | 2.85E2 |