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Author(s):   Buravtsev, N.N.; Grigor'ev, A.S.; Kolbanovskii, Y.A.; Ovsyannikov, A.A.
Title:   Intermediates and initial stages in pyrolysis of ethanes: CF3CH2F, CHF2CHF2, and CF3CH2Cl
Journal:   Dokl. Phys. Chem. (Engl. Transl.)
Volume:   339
Page(s):   230 - 234
Original page:   616
Year:   1994
Reference type:   Journal article
Squib:   1994BUR/GRI230-234

Reaction:   CF3CH2FC2HF3 + HF
Reaction order:   1
Temperature:   1000 - 1280 K
Rate expression:   2.0x1012 [s-1] e-280198 [±2802 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1000 4.63E-3
1025 1.05E-2
1050 2.30E-2
1075 4.86E-2
1100 9.90E-2
1125 1.96E-1
1150 3.75E-1
1175 7.00E-1
1200 1.27E0
1225 2.26E0
1250 3.91E0
1275 6.64E0
1280 7.36E0