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Accessibility information
Author(s):   Wampler, F.B.; Kuntz, R.R.
Title:   Some hydrogen abstraction reactions of the trichloromethyl radical
Journal:   Int. J. Chem. Kinet.
Volume:   3
Year:   1971
Reference type:   Journal article
Squib:   1971WAM/KUN283

Reaction:   Methylcyclohexane + ·CCl3 → Other Products + CHCl3
Reaction order:   2
Reference reaction:   ·CCl3 + ·CCl3CCl3CCl3
Temperature:   374 - 442 K
Pressure:  0.33 bar
Rate expression:   9.33x10-13 [cm3/molecule s] e-41406 [±8314472 J/mole]/RT
Uncertainty:   1.82000005
Bath gas:   Methylcyclohexane
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
374 1.54E-18
375 1.59E-18
400 3.66E-18
425 7.60E-18
442 1.19E-17