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Author(s):   Berasategui, M.; Arguello, G.A.; Burgos Paci, M.A.
Title:   Reaction of Methyl Fluoroformyl Peroxycarbonate (FC(O)OOC(O)OCH3) with CI Atoms: Formation of Hydro-ChloroFluoro-Peroxides
Journal:   J. Phys. Chem. A
Volume:   121
Page(s):   7469 - 7476
Year:   2017
Reference type:   Journal article
Squib:   2017BER/ARG7469-7476

Reaction:   FC(O)OOC(O)OCHCl2 + ·Cl → FC(O)OOC(O)OCCl2· + HCl
Reaction order:   2
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   1.7x10-14 [±6.0x10-15 cm3/molecule s]
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)

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