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Author(s):   Berkley, R.E.; Safarik, I.; Gunning, H.E.; Strausz, O.P.
Title:   Arrhenius parameters for the reactions of methyl radicals with silane and methylsilanes
Journal:   J. Phys. Chem.
Volume:   77
Year:   1973
Reference type:   Journal article
Squib:   1973BER/SAF1734

Reaction:   CH3SiD3 + CD3 → Other Products + CD4
Reaction order:   2
Reference reaction:   CD3 + CD3C2D6
Temperature:   295 - 425 K
Rate expression:   5.13x10-12 [cm3/molecule s] e-38496 [±2311 J/mole]/RT
Uncertainty:   2.200000047683716
Bath gas:   CD3N2CD3
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
295 7.83E-19
300 1.02E-18
325 3.34E-18
350 9.23E-18
375 2.23E-17
400 4.82E-17
425 9.53E-17