Author(s):   Li, S.H.; Larson, C.A.; Buchan, N.I.; Stringfellow, G.B.
Title:   Pyrolysis of tertiarybutylphosphine
Journal:   J. Electron. Mater.
Volume:   18
Page(s):   457 - 462
Year:   1989
Reference type:   Journal article
Squib:   1989LI/LAR457-462

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	Order
1989LI/LAR457-462	(CH₃)3CPH → tert-C₄H₉ + PH	648 - 723	3.16E17	2.29E05	1
1989LI/LAR457-462	tert-C₄H₉ + tert-C₄H₉PH₂ → (CH₃)3CPH + iso-C₄H₁₀	648 - 723	1.05E-12	7.21E04	2
1989LI/LAR457-462	tert-C₄H₉PH₂ → tert-C₄H₉ + PH₂	648 - 723	3.16E17	2.64E05	1

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