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Author(s):   Tovar, C. M.; Blanco, M. B.; Barnes, I.; Wiesen, P.; Teruel, M. A.
Title:   Gas-phase reactivity study of a series of hydrofluoroolefins (HFOs) toward OH radicals and Cl atoms at atmospheric pressure and 298 K
Journal:   Atmos. Environ.
Volume:   88
Page(s):   107 - 114
Year:   2014
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2014TOV/BLA107-114

Reaction:   (CF3)2C=CH2 + ·Cl → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   3.5x10-11 [±8.5x10-12 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Isobutene and 1-butene were used as reference compounds. The quoted uncertainties for the rate coefficient are a combination of the 2σ statistical errors from the linear regression analysis plus an additional contribution of the errors in the reported rate coefficients of the reference compounds.

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