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Title: On the mechanism of homogeneous decomposition of the chlorinated silanes. Chain reactions propagated by divalent silicon species
Journal: J. Phys. Chem. A
Volume: 102
Page(s): 1542 - 1549
Year: 1998
Reference type: Journal article
Squib: 1998SWI/CAR1542-1549
Reaction:
Si2Cl6 → SiCl4 + SiCl2
Reaction order:
1
Temperature:
800 - 1300
K
Rate expression:
1.58x1014 [s-1] e-204536 [J/mole]/RT
Category: Theory
Data type:
Transition state theory
Pressure dependence:
Rate constant is high pressure limit
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 800 | 6.98E0 |
| 850 | 4.26E1 |
| 900 | 2.13E2 |
| 950 | 8.97E2 |
| 1000 | 3.27E3 |
| 1050 | 1.06E4 |
| 1100 | 3.06E4 |
| 1150 | 8.10E4 |
| 1200 | 1.98E5 |
| 1250 | 4.48E5 |
| 1300 | 9.56E5 |