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Accessibility information
Author(s):   Swihart, M.T.; Carr, R.W.
Title:   On the mechanism of homogeneous decomposition of the chlorinated silanes. Chain reactions propagated by divalent silicon species
Journal:   J. Phys. Chem. A
Volume:   102
Page(s):   1542 - 1549
Year:   1998
Reference type:   Journal article
Squib:   1998SWI/CAR1542-1549

Reaction:   Si2Cl6SiCl4 + SiCl2
Reaction order:   1
Temperature:   800 - 1300 K
Rate expression:   1.58x1014 [s-1] e-204536 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory
Pressure dependence:   Rate constant is high pressure limit

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
800 6.98E0
850 4.26E1
900 2.13E2
950 8.97E2
1000 3.27E3
1050 1.06E4
1100 3.06E4
1150 8.10E4
1200 1.98E5
1250 4.48E5
1300 9.56E5