Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Wu, E-Chung; Rodgers, A.S.
Title:   The gas-phase kinetics of the reaction of 1,1,1-trifluoroethyl iodine with HI: The C-I bond dissocation energy in 2,2,2-trifluoroethyl iodide
Journal:   Int. J. Chem. Kinet.
Volume:   5
Year:   1973
Reference type:   Journal article
Squib:   1973WU/ROD1001

Reaction:   CF3CH2I + ICF3CH2 + I2
Reaction order:   2
Temperature:   525 - 602 K
Pressure:  1.60E-2 - 4.67E-2 bar
Rate expression:   5.25x10-10 [cm3/molecule s] e-83145 [±831 J/mole]/RT
Uncertainty:   1.25999999
Bath gas:   CF3CH2I
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
525 2.80E-18
550 6.66E-18
575 1.47E-17
600 3.03E-17
602 3.20E-17