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Accessibility information
Author(s):   Forgeteg, S.; Berces, T.; Dobe, S.
Title:   The kinetics and mechanism of n-butyraldehyde photolysis in the vapor phase at 313 nm
Journal:   Int. J. Chem. Kinet.
Volume:   11
Year:   1979
Reference type:   Journal article
Squib:   1979FOR/BER219

Reaction:   CH3CH2CH2CHO + 1-C3H7C3H8 + C2H5CH(·)CHO
Reaction order:   2
Reference reaction:   1-C3H7 + 1-C3H71-C6H14
Temperature:   273 - 529 K
Pressure:  0.13 bar
Rate expression:   6.61x10-14 [cm3/molecule s] e-40990 [±2868 J/mole]/RT
Uncertainty:   3.16000009
Bath gas:   CH3CH2CH2CHO
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
273 9.49E-22
275 1.08E-21
300 4.82E-21
325 1.71E-20
350 5.04E-20
375 1.29E-19
400 2.93E-19
425 6.06E-19
450 1.15E-18
475 2.05E-18
500 3.45E-18
525 5.52E-18
529 5.93E-18