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Accessibility information
Author(s):   Clyne, M.A.A.; Nip, W.S.
Title:   Study of elementary reactions by atomic resonance absorption with a non-reversed source. Part 1 - The reaction Cl+O3→’ClO+O2
Journal:   J. Chem. Soc. Faraday Trans. 2
Volume:   72
Page(s):   838 - 847
Year:   1976
Reference type:   Journal article
Squib:   1976CLY/NIP838-847

Reaction:   O3 + ·ClO2 + ClO
Reaction order:   2
Temperature:   221 - 629 K
Rate expression:   5.18x10-11 [cm3/molecule s] e-3467 [±243 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
221 7.85E-12
225 8.12E-12
250 9.77E-12
275 1.14E-11
300 1.29E-11
325 1.44E-11
350 1.57E-11
375 1.70E-11
400 1.83E-11
425 1.94E-11
450 2.05E-11
475 2.15E-11
500 2.25E-11
525 2.34E-11
550 2.43E-11
575 2.51E-11
600 2.59E-11
625 2.66E-11
629 2.67E-11