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Accessibility information
Author(s):   DeMore, W.B.
Title:   Tests of stratospheric models: The reactions of atomic chlorine with O3 and CH4 at low temperature
Journal:   J. Geophys. Res.
Volume:   96
Page(s):   4995 - 5000
Year:   1991
Reference type:   Journal article
Squib:   1991DEM4995-5000

Reaction:   O3 + ·ClO2 + ClO
Reaction order:   2
Reference reaction:   CH4 + ·Cl·CH3 + HCl
Reference reaction order:   2
Temperature:   197 - 217 K
Pressure:  1.01 - 3.04 bar
Rate expression:   3.33 e9312 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
197 9.81E2
200 9.01E2
217 5.81E2