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Title: Kinetic study of the reactions Na + O2 N2 and Na + N2O over an extended temperature range
Journal: J. Phys. Chem.
Volume: 93
Page(s): 3135 - 3140
Year: 1989
Reference type: Journal article
Squib: 1989PLA/RAJ3135-3140
Reaction:
Na + N2O → N2 + NaO
Reaction order:
2
Temperature:
280 - 850
K
Pressure: 2.67E-2 - 6.67E-2 bar
Rate expression:
2.81x10-10 [±3.16x10-11 cm3/molecule s] e-13220 [±397 J/mole]/RT
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Laser induced fluorescence
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 280 | 9.59E-13 |
| 300 | 1.40E-12 |
| 350 | 2.99E-12 |
| 400 | 5.27E-12 |
| 450 | 8.20E-12 |
| 500 | 1.17E-11 |
| 550 | 1.56E-11 |
| 600 | 1.98E-11 |
| 650 | 2.43E-11 |
| 700 | 2.90E-11 |
| 750 | 3.37E-11 |
| 800 | 3.85E-11 |
| 850 | 4.32E-11 |