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Title: High-temperature thermal decomposition of isobutane and n-butane behind shock waves
Journal: J. Phys. Chem. A
Volume: 108
Page(s): 4247 - 4253
Year: 2004
Reference type: Journal article
Squib: 2004OEH/DAV4247-4253
Reaction:
iso-C4H10 → 2-C3H7 + ·CH3
Reaction order:
2
Temperature:
1320 - 1560
K
Rate expression:
4.0x10-5 [cm3/molecule s] e-220001 [J/mole]/RT
Category: Experiment
Data type:
RRK(M) extrapolation
Pressure dependence:
Rate constant is low pressure limit
Comments:
RRKM-Master Equation model created on the basis of experimental data obtained in shock tube experiments in the same work.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 1320 | 7.88E-14 |
| 1325 | 8.50E-14 |
| 1350 | 1.23E-13 |
| 1375 | 1.76E-13 |
| 1400 | 2.48E-13 |
| 1425 | 3.45E-13 |
| 1450 | 4.75E-13 |
| 1475 | 6.48E-13 |
| 1500 | 8.74E-13 |
| 1525 | 1.17E-12 |
| 1550 | 1.54E-12 |
| 1560 | 1.72E-12 |