NIST Chemical Kinetics Database

Author(s):   Patrick, R.; Golden, D.M.
Title:   Termolecular reactions of alkali metal atoms with O₂ and OH
Journal:   Int. J. Chem. Kinet.
Volume:   16
Page(s):
Year:   1984
Reference type:   Journal article
Squib:   1984PAT/GOL1567

Reaction:   ·OH + Li → LiOH
Reaction order:   3
Temperature:   200 - 2000 K
Rate expression:   6.84x10^-31 [cm⁶/molecule² s] (T/298 K)^-2.20 e^{-407 [J/mole]/RT}
Bath gas:   N2
Category: Experiment
Data type:   Derived from detailed balance/reverse rate

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Rate constant values calculated from the Arrhenius expression:

T (K)	k(T) [cm⁶/molecule² s]
200	1.29E-30
300	5.72E-31
400	3.17E-31
500	1.99E-31
600	1.35E-31
700	9.74E-32
800	7.33E-32
900	5.69E-32
1000	4.54E-32
1100	3.70E-32
1200	3.06E-32
1300	2.58E-32
1400	2.20E-32
1500	1.89E-32
1600	1.64E-32
1700	1.44E-32
1800	1.27E-32
1900	1.13E-32
2000	1.01E-32