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Author(s):   Stothard, N.D.; Walker, R.W.
Title:   Arrhenius parameters for the addition of HO2 radicals to (E)-but-2-ene over the range 400-520°C
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   86
Year:   1990
Reference type:   Journal article
Squib:   1990STO/WAL2115

Reaction:   (E)-2-C4H8 + HO22,2-dimethyloxirane + ·OH
Reaction order:   2
Reference reaction:   CH3CH=CH2 + HO2Methyloxirane + ·OH
Reference reaction order:   2
Temperature:   673 - 793 K
Pressure:  8.00E-2 bar
Rate expression:   4.0x10-1±1.3x10-1 e12638 [±2644 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
673 3.83E0
675 3.80E0
700 3.51E0
725 3.26E0
750 3.04E0
775 2.84E0
793 2.72E0