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Title: Chemical kinetic data base for combustion chemistry. Part 4. Isobutane
Journal: J. Phys. Chem. Ref. Data
Volume: 19
Page(s): 1 - 68
Year: 1990
Reference type: Journal article
Squib: 1990TSA1-68
Reaction:
tert-C4H9 → Isobutene + H·
Reaction order:
1
Temperature:
300 - 2500
K
Rate expression:
8.3x1013 [s-1] e-159638 [J/mole]/RT
Uncertainty:
3.0
Category: Review
Data type:
Extensive literature review
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 300 | 1.33E-14 |
| 400 | 1.18E-7 |
| 500 | 1.75E-3 |
| 600 | 1.05E0 |
| 700 | 1.02E2 |
| 800 | 3.13E3 |
| 900 | 4.51E4 |
| 1000 | 3.81E5 |
| 1100 | 2.18E6 |
| 1200 | 9.34E6 |
| 1300 | 3.20E7 |
| 1400 | 9.18E7 |
| 1500 | 2.29E8 |
| 1600 | 5.10E8 |
| 1700 | 1.03E9 |
| 1800 | 1.93E9 |
| 1900 | 3.39E9 |
| 2000 | 5.62E9 |
| 2100 | 8.88E9 |
| 2200 | 1.35E10 |
| 2300 | 1.97E10 |
| 2400 | 2.78E10 |
| 2500 | 3.83E10 |