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Author(s):   Park, J.; Nguyen, H.MT.; Xu, Z.F.; Lin, M.C.
Title:   Kinetic Study of the 2-Naphthyl (C10H7) Radical Reaction with C2H2
Journal:   J. Phys. Chem. A
Volume:   113
Page(s):   12199 - 12206
Year:   2009
Reference type:   Journal article
Squib:   2009PAR/NGU12199-12206

Reaction:   C2H2 + 2-Naphthalenyl → Products
Reaction order:   2
Temperature:   303 - 448 K
Pressure:  5.33E-2 bar
Rate expression:   5.58x10-13 [±1.05x10-13 cm3/molecule s] e-6793 [±283 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Cavity ringdown spectroscopy was used to monitor C10H7O2 formed in a competing reaction in real time.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
303 3.76E-14
325 4.52E-14
350 5.41E-14
375 6.32E-14
400 7.24E-14
425 8.16E-14
448 9.01E-14