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Author(s):   Goulay, F.; Trevitt, A.J.; Meloni, G.; Selby, T.M.; Osborn, D.L.; Taatjes, C.A.; Vereecken, L.; Leone, S.R.
Title:   Cyclic Versus Linear Isomers Produced by Reaction of the Methylidyne Radical (CH) with Small Unsaturated Hydrocarbons
Journal:   J. Am. Chem. Soc.
Volume:   131
Page(s):   993 - 1005
Year:   2009
Reference type:   Journal article
Squib:   2009GOU/TRE993-1005

Reaction:   C2H2 + ·CH + CH2=C=C:
Reaction order:   2
Reference reaction:   C2H2 + ·CH → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  5.33E-3 bar
Rate expression:   9.5x10-2
Rate constant is an upper limit.
Category:  Theory
Data type:   Transition state theory
Pressure dependence:   None reported
Comments:   Reaction potential energy surface was studied using quantum chemistry and branching fractions were calculated using RRKM and master equation.

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