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Author(s):   Duncan, F.J.; Trotman-Dickenson, A.F.
Title:   The reactions of phenyl radicals from the photolysis of acetophenone and the strength of the C-H bond in benzene
Journal:   J. Chem. Soc.
Year:   1962
Reference type:   Journal article
Squib:   1962DUN/TRO4672

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1962DUN/TRO4672   CH4 + PhenylBenzene + ·CH3  550 - 680   1.32E-12       4.64E04      2
  1962DUN/TRO4672   Cyclopropane + PhenylBenzene + Cyclopropyl  550 - 680   4.17E-13       3.56E04      2
  1962DUN/TRO4672   iso-C4H10 + Phenyl → Other Products + Benzene  550 - 680   1.05E-12       2.80E04      2
  1962DUN/TRO4672   1-Phenylethanone + ·CH3 → Other Products + CH4  550 - 680   8.32E-14       3.09E04      2
  1962DUN/TRO4672   1-Phenylethanone + Phenyl → Other Products + Benzene  550 - 680   6.61E-13       2.59E04      2
  1962DUN/TRO4672   1-Phenylethanone + PhenylBiphenyl + CH3CO  550 - 680   5.65E-15       2.46E04      2

Search returned 6 records.