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Author(s):   Duncan, F.J.; Trotman-Dickenson, A.F.
Title:   The reactions of phenyl radicals from the photolysis of acetophenone and the strength of the C-H bond in benzene
Journal:   J. Chem. Soc.
Page(s):  
Year:   1962
Reference type:   Journal article
Squib:   1962DUN/TRO4672

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1962DUN/TRO4672   CH4 + PhenylBenzene + ·CH3  550 - 680   1.32E-12       4.64E04      2
  1962DUN/TRO4672   Cyclopropane + PhenylBenzene + Cyclopropyl  550 - 680   4.17E-13       3.56E04      2
  1962DUN/TRO4672   iso-C4H10 + Phenyl → Other Products + Benzene  550 - 680   1.05E-12       2.80E04      2
  1962DUN/TRO4672   1-Phenylethanone + ·CH3 → Other Products + CH4  550 - 680   8.32E-14       3.09E04      2
  1962DUN/TRO4672   1-Phenylethanone + Phenyl → Other Products + Benzene  550 - 680   6.61E-13       2.59E04      2
  1962DUN/TRO4672   1-Phenylethanone + PhenylBiphenyl + CH3CO  550 - 680   5.65E-15       2.46E04      2

Search returned 6 records.