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Author(s):   Baker, R.R.; Baldwin, R.R.; Walker, R.W.
Title:   Addition of C3H8, n- and i-C4H10 to slowly reacting mixtures of hydrogen and oxygen at 480°C
Journal:   Trans. Faraday Soc.
Volume:   66
Page(s):  
Year:   1970
Reference type:   Journal article
Squib:   1970BAK/BAL2812

Reaction:   iso-C4H10 + ·OH → Other Products + H2O
Reaction order:   2
Reference reaction:   H2 + ·OHH2O +
Temperature:   730 - 780 K
Pressure:  0.33 - 0.89 bar
Rate expression:   2.32x10-10 [cm3/molecule s] e-11640 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
730 3.42E-11
750 3.59E-11
775 3.82E-11
780 3.86E-11