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Author(s):   Donahue, N.M.; Anderson, J.G.; Demerjian, K.L.
Title:   New rate constants for ten OH alkane reactions from 300 to 400 K: an assessment of accuracy
Journal:   J. Phys. Chem. A
Volume:   102
Page(s):   3121 - 3126
Year:   1998
Reference type:   Journal article
Squib:   1998DON/AND3121-3126

Reaction:   iso-C4H10 + ·OH → Other Products + H2O
Reaction order:   2
Temperature:   300 - 390 K
Pressure:  4.00E-2 bar
Rate expression:   6.26x10-12 [cm3/molecule s] e-2669 [±80.07 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Laser induced fluorescence

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 2.15E-12
325 2.33E-12
350 2.50E-12
375 2.66E-12
390 2.75E-12