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Author(s):   Gray, P.; Jones, A.
Title:   Methyl radical reactions with ethylamine and deuterated ethylamines
Journal:   Trans. Faraday Soc.
Volume:   62
Year:   1966
Reference type:   Journal article
Squib:   1966GRA/JON112

Reaction:   ·CH3 + CH3CH2ND2 → CH3CH2ND· + CH3D
Reaction order:   2
Reference reaction:   ·CH3 + ·CH3C2H6
Temperature:   383 - 453 K
Rate expression:   1.83x10-14 [cm3/molecule s] e-31928 [±1596 J/mole]/RT
Uncertainty:   1.62
Bath gas:   (CH3N)2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
383 8.08E-19
400 1.24E-18
425 2.18E-18
450 3.59E-18
453 3.80E-18