NIST Chemical Kinetics Database

Author(s):   Maccoll, A.; Wong, S.C.
Title:   Gas-phase eliminations. Part VIII. The effect of β-methylation on the pyrolysis of some t-alkyl chlorides
Journal:   J. Chem. Soc. B
Page(s):   1492 - 1494
Year:   1968
Reference type:   Journal article
Squib:   1968MAC/WON1492-1494

Reaction:   tert-C₄H₉Cl → Isobutene + HCl
Reaction order:   1
Temperature:   563 - 604 K
Rate expression:   5.89x10¹³ [s^-1] e^{-188739 [J/mole]/RT}
Bath gas:   tert-C4H9Cl
Category: Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

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Rate constant values calculated from the Arrhenius expression:

T (K)	k(T) [s^-1]
563	1.82E-4
575	4.22E-4
600	2.18E-3
604	2.81E-3