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Title: Gas-phase eliminations. Part VIII. The effect of β-methylation on the pyrolysis of some t-alkyl chlorides
Journal: J. Chem. Soc. B
Page(s): 1492 - 1494
Year: 1968
Reference type: Journal article
Squib: 1968MAC/WON1492-1494
Reaction:
Butane, 2-chloro-2,3,3-trimethyl- → (CH3)3CC(CH3)=CH2 + HCl
Reaction order:
1
Temperature:
523 - 568
K
Rate expression:
6.31x1013 [s-1] e-175435 [J/mole]/RT
Bath gas:
Butane, 2-chloro-2,3,3-trimethyl-
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 523 | 1.90E-4 |
| 525 | 2.22E-4 |
| 550 | 1.38E-3 |
| 568 | 4.64E-3 |