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Title: Propyne Pyrolysis in a Flow Reactor: An Experimental, RRKM, and Detailed Kinetic Modeling Study
Journal: J. Phys. Chem. A
Volume: 103
Page(s): 5889 - 5899
Year: 1999
Reference type: Journal article
Squib: 1999DAV/LAW5889-5899
Reaction:
·CH3 + ·CH2C≡CH → 1,2-butadiene
Reaction order:
2
Temperature:
1200 - 1500
K
Rate expression:
2.49x10-12 [cm3/molecule s]
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Pressure dependence:
Rate constant is high pressure limit
Experimental procedure:
Flow tube - Data taken vs distance
Excitation technique:
Thermal
Time resolution:
In real time
Analytical technique:
Gas chromatography
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