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Title: Kinetics of the reactions of methyl, ethyl, isopropyl, and tert-butyl radicals with molecular chlorine
Journal: J. Phys. Chem.
Volume: 90
Page(s): 2987 - 2991
Year: 1986
Reference type: Journal article
Squib: 1986TIM/GUT2987-2991
Reaction:
tert-C4H9 + Cl2 → tert-C4H9Cl + ·Cl
Reaction order:
2
Temperature:
298 - 498
K
Pressure: 1.87E-3 - 2.40E-3 bar
Rate expression:
3.99x10-11 [cm3/molecule s] e41.57 [±8314472 J/mole]/RT
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 298 | 4.05E-11 |
| 300 | 4.05E-11 |
| 325 | 4.05E-11 |
| 350 | 4.04E-11 |
| 375 | 4.04E-11 |
| 400 | 4.04E-11 |
| 425 | 4.03E-11 |
| 450 | 4.03E-11 |
| 475 | 4.03E-11 |
| 498 | 4.03E-11 |