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Title: Kinetics and thermodynamics of the reaction SF6 = SF5 + F
Journal: J. Chem. Phys.
Volume: 96
Page(s): 4272 - 4282
Year: 1992
Reference type: Journal article
Squib: 1992TSA/HER4272-4282
Reaction:
SF5 + ·F → SF6
Reaction order:
2
Temperature:
1700 - 2000
K
Rate expression:
1.0x10-11 [cm3/molecule s] (T/298 K)-1.00
Bath gas:
Ar
Category: Review
Data type:
Extensive literature review
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 1700 | 1.76E-12 |
| 1725 | 1.73E-12 |
| 1750 | 1.71E-12 |
| 1775 | 1.68E-12 |
| 1800 | 1.66E-12 |
| 1825 | 1.64E-12 |
| 1850 | 1.61E-12 |
| 1875 | 1.59E-12 |
| 1900 | 1.57E-12 |
| 1925 | 1.55E-12 |
| 1950 | 1.53E-12 |
| 1975 | 1.51E-12 |
| 2000 | 1.49E-12 |