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Accessibility information
Author(s):   Ashmore, P.G.; Spencer, M.S.
Title:   Concurrent molecular and chlorine atom mechanisms in the reversible dissociation of nitrosyl chloride
Journal:   Trans. Faraday Soc.
Volume:   55
Page(s):   1868 - 1883
Year:   1959
Reference type:   Journal article
Squib:   1959ASH/SPE1868-1883

Reaction:   NOClNO + ·Cl
Reaction order:   2
Temperature:   523 - 573 K
Pressure:  5.33E-3 - 0.31 bar
Rate expression:   3.99x10-8 [cm3/molecule s] e-149660 [J/mole]/RT
Bath gas:   Cl2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Pressure measurement

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
523 4.50E-23
525 5.13E-23
550 2.44E-22
573 9.07E-22